Thermo-electric generator



2 Sheets-Sheet 1.

(No Model.)

C. S. BRADLEY.

THERMO ELECTRIC GENERATOR. y

Patented Feb. 4, 1890,.

(No Model.) 2 Sheets-Sheet 2.

C. S. BRADLEY.

THERMO ELEGTRIG GENERATOR.

UNITEDv STATES PATENT OFFICE.

' CHARLES BRADLEY. 0F YONKERS, NEW YORK.

TH ERMo- ELi-:crmc c :NERA-ro n.

SPECIFICATION forming para of Letters Patent No. 420,764, dated February 4, 189,0.

Application mum 1'1, 1889.

To alllwhom it may concern.'

Be it known that I, CHARLES S.BRADI1EBI,

a citizen of the United States, residing at of the invention, such `as will enable others if skilled` in the art to which it make and use the same. This invention relates to.` theconsti",uctin'r of thermo-electric generators, 'and has-for its g object certain improvementsiin the form of the generator, affecting its cost and efficiency and mechanicalI strength. Heretofore thermoelectric pairs and' batteries have been constructed of ,metals or a1- loys which remain in the solid statewhile'in` operation. Ithas been found that the elec'- tro-motive force is higher 'ati a given diifen. ence of temperature between the hot andcold junctions in the case o f certain alloys than where simple metals areused foreach mem-, ber of the thermo-electriccouple.'l It has been found, however, that the .alloys which have proved the most eiiicient with respect-'to the generation of electrical energy are mechanically weak, and are liable not only to ybecome cracked from slight causes, but even to be. come broken. The consequence is that batf teries and lgenerators constructed of these fragile alloys must be handled with extreme'- appertains to .care in order to have them preserve theirfef-I fectiveness and must be operated at' comparatively low temperatures.

My invention therefore consists in certain arrangements and combinationsinvolving the use of a metal or alloy at-tlie .thermo-elecftric' junctions, and so disposedthatthe metal or alloy may be fused without injuring, subsA stantially as hereinafter .fully described and claimed.

- In the drawings which form part of this specification, Figure' 1 isa diagram ofone ofthe simplest forms `of my invention. Fig. 2 is a sectional diagram illustrating theinven*-- tion in another form.l Fig. 3 is still another,

modification-of the-mere form.` Figs. 4,15, -and 6 are Arespectively plan and side.; eleva-A tions and a; longitudinal section of the corn-A plete and developed type of therlno'-electric4 In the modification vshown at Fig.

sean reelecto. mq mada generator which I'have devised i'nu-ccoro:`

ance with the Apresent invention. Fig. 7 is ai.

transverse vertical section of what I may term the heater. Fig. 8 is a similar section of 'what I"term the coolen Fig. 9 is va face view of .the non-conducting washer which forms the fusion-cellof the apparatus- Fig. 10 is an. enlarged section showing a modified formof fusion-cell. 'Fig'. 11 is .a plan view of .a-'series-of.-.such generators' placed oneabove the 'etn'ergand Fig.,1 2'is a side'elevation illustratingthe'samein-conuectionwith a furnace .'s'tructure.` j 'j' In Fig l 'I construct a plate of iron l, with annular projections 2 and 3, which form pockets for the reception of small tire-clay 'rings 4. 5, and I lay onthe plate 1 a moder-' '-ately-.thic'k layerof a non-conductor of elec` tricity-such, for eXani'ple,Zas asbestus# which isf also a poor thermal conductor. Above theseI-place' the coolers 7- 8, respectively,- preferably being constructed of iron in the form o f a vessel adaptedto con-l tain water, and each having on its under face .a nipple or projection 9 l0, respectively, dipping into the'cavityformed by the clay-rings .4 5,. Into 'the ,cell formed by the ring 4,1 pourthe molten alloy which itisdesired to use, and into the cell formed by the ring 5, I

pour moltenbismuth or other` metal. Underneath the plate 1, Iintrodnce a suitable'source iron coolers 7 8, and these can' be connected '2 the into -the circuit i-n any desiredlway.

cooler 7 has its nipple'9 hollow and forming Aa part of the water-chamber of thecooler.- The heater ,l is directlyformed into a c up shape, containing the alloy, and the heat Isource' l'lis applied directly to the bottomof such vessel. tends an iron rod 13, which terminates in a From the yside of the cup 1 ex# :of heat-such, for instance, as the gas-burn'- cup'14, carrying water, so'as to keep the terminal cool belonging to the alloy element."

In Fig. 3 the devices are'arranged lto be nested, and 'the'l construction is that' of a rpo f double structure composed of the upper ironv cup 15 andthe. lower iron cup 16, united by the bracket 17,' A pairof these maybe used'. together,l the cup 1 5 o f one fitting down into lIo Jas

the cup 16 of the other, and the space in en p 16 between it and the interior cup 15 of thc adjoining element being vmade the receptacle of the fused alloy. The heat source 11 is applied to each of the cups `16' and water is placed in the interior cups 15.

Although the foregoing forms are repre-c sentative of the principles of my invention, l'Iprefer the form fully shown in Figs. LM012, 4 inclusive',as being more especially adapted to practical work. This construction isas follows:` Y

I take a central heater consisting of the inclosure 18, which may be of any suitable form, and'has crossing it in 'the interior a number of heating-surfaces 19, which I prefer to make thinncstat the center and gradually thickeningup at the opposite ends, and toward such ends the walls of the heater t18 also grow thicker for the purpose of allording `conductibility proportionate to the amount ofv heat that has to be conducted as the point of concentration. is approached.4 This point of concentration is found at the projections 20, which end in the flanges 21. The whole structure 18, 19, 20, and 2l is made of ordinary cast-iron and is arranged with any suitable source of heat below it-such as one or more gas-burners or a furnace of suitable character. To each of the flanges 21, I bolt the coolers 22, (the bolts being insulated; as shown,) which I prefer to make of cast-iron, with internal cooling-surfaces, gradually di- -nlinishing in cross-section as they recede from the point of attachment to flange 21. Between the iiange 21 and the cooler 22, Il place an annular 'washer or packing 23 of such material as is not a conductor of electricity, and preferably also a poor conductor of heat. One side of this packing is cut through, so as to form a slot communicating from the exterior to the interior of the washer, and when the heater 1s bolted up into the position, as shown in the variousgfigures, the opening at.the center of the washer 23' forms a dat circular cavity or cell, with which communication can be had from the outside by means of the slot or opening 24. Into one of the cavities thus formed-for instance, that at the left-I pour melted alloy" of cadmium and antimony, and into the other-namely, the'one at the right- I pour melted bismuth. Upon the application of a sufficient amount of -heat from some external source to the heater 18, 19, and 20 the apparatus becomes a thermo-electric generator, of which the hot junction may be said to be composed of the` molten bismuth and the alloy of cadmium andantimony, the mass of iron 18 19 20, which lies between these two bodies, being practically inert and serving merely the purpose of conveying the heat to the hot junction. At the same time, however, the said mass. of Viron is also a portion of the electric circuit; but on account of its form and proportion's its conductivity is so great e1ectrically as to become practically an immaterial factor in the resistant-.e of the entire cirflow of electric, current will be very low. As. a matter of fact, it may be well to state that a cell so formed, one inch in diameter 'and one-eighth inch long, containing the abovementioned alloy, will -have an electrical rcsistance of less than .0001 of an ohm, and in the pair above mentioned the electro-motive force will be about .073 volt. Consequently, if the external resistance be kept low enough, the volume of current may be allowed to reach very large proportionsin the generator itself without the possibility of doing any harm. l

It will be observed that the molten condition of the metal or alloy in the fusion-cell permits a very high temperature tobe reached at the hot junction and .a very low temperature at the cold junction; yet the act-ive. portion of the circuit is exceedingly short. With a proper amount of cooling-surface in the coolers 22 and the application of Water as a means of carrying otf the heat it is possible to maintain .the surface of the metal in the fusion-cell in a solid state along the surface which is in contact with the cooler 22; and, being thus able to maintain a high temperature at the hot junction andy a low temperature at the cold junction, I can obtain a very high eciency in the generator as a whole. In the modification shown at Figs. 9 and 10 by special construction of the cell-forming washer 23, I am enabled'to widen out or expand the actual surface of the coldjunction without materially altering the other conditions above noted, or in any way detracting from the advantages. belonging to the principle.

Another advantage of the foregoing construction is the small quantity of Working metals which are required, thus insuring the small first cost, short electric circuit, and minimum internal resistance. By far the largest portion of the entire structure is made of inactive material-such, for instance,v as

cast-iron-which notenly serves to gather and deliver the heat, but also forms the electrical connections and the retaining Walls for the fused metals, and by the use of cast-iron for the foregoing purposes I can safely use a very 4high initial temperature, and thereby attain a maximum efficiency, such as is impossible in such structures as require the 'direct conhot junction, since in the latter case a limitation is placed by the melting-point of the material, which thus forms a portion of the mechanical structure of the generator.

I do not herein limit the scope of this invenroo ' tact of the two thermo-electric bodies at the tion to any particular metals or alloys to be used in the fusion-cell of a thermo-electric generator, as a great Variety of metals and alloys are now Well known and can be used to good eect in accordance with the invention hereinbefore described.

It is desirable to use a thin insulating annular washer a on each side of the cell-forming washer 23, to prevent interference of action by the neck of alloy or met-al rising from.

`element which remains solid at the highest working temperature, in combination with an element which becomes fused at lthe hot junction.

2. A thermo-electric generator havingan element which remains solid at the highest working temperature, in combination with an element which is fused at the hot junction and solid at the cold junction.

3. A thermo-electric Vgenerator having two fusible elements in contact with an interposed electrically-conductive heater adapted to fuse said elements at the surfaces of contact therewith.

4. A thermo-electric generator having a fusible element in contact with a practically infusible electrically-conductive heater;

5. A thermo-electric generator having a fusibleelement in contact at one end with a' practically infusible electrically-conductiveheater and .at the other end with an electrically-conductive cooler.

6. .A thermo-electric generator comprising a fusion-cell containing a fusible metal or alloy and constituted by two adjacent conductive bodies insulated from'each other,

and a source ofheat applied to one of said bodies.

7. A thermo-electric generator comprising a'fusion-cell containing a fusible metal or alloy and constituted by'two adjacent conductive bodies with an interposed insulating ring or annulus, and a source of heatapplied -to one of said bodies of metal.

8J A thermo-electric generatorhaving a fused element in the form substantially of a disk axially presented to the electrical circuit.

9. A thermolelectric generator having an element of fusible metal or alloy of disk or plate form, .in combination with heating and cooling devices, respectively, applied to the faces of the disk.

10. A thermo-electric generator comprsi ng two fusible elements and an interposed metallc heater adapted to receive heat and disy tribute it to' the fusible elements.

11. A thermo-electric generator comprising Vlo'ron E. BURKE, Gmo, WOBTHINGTON.

two thermo-electric elements joined by an in- 

